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95_GSX previously said:
The production of ULSD doesn't use much water really.
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Correct. Overall, for an older refinery with minimal improvements, the requirement of process - treated - water to crude is approximately 1:1. The consumption is referred to as steam generation, desalting operation, cooling tower water makeup and blowdown, etc, and as more and more water loops can be closed and recycled, the net water use declines
Refineries differ in design. Older refineries, typical of the North American market, have the most process water consumption due to just older, less efficient designs. Modern designs use far less net process water. Let's use around 130,000 bpd, that is a good size facility.
Eg, a refinery made in the last 20 years will use about 8 million litres of process water per day. As the crude input is around 130,000 bpd, that works out to 20,670,000 litres per day crude consumption. A new refinery with all modern digital process bus control, the process water consumption will trend to under 4 million litres per day.
A lot more can be done to recycle from residuum. Membrane technology can be used to recover and recycle process water
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95_GSX previously said:
We inject water into the process to clean/remove salts that are deposited inside heat exchangers.
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Water/chemicals are also used in the desalter. It's difficult to keep hx clean, especially plate hx. It's a major PITA to take apart a plate hx to clean it, but that must be done
Boiler operations are an important part of the overall refinery process. Steam is needed for many parts especially the dist. tower
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95_GSX previously said:
The removal of sulfur is done with chemisty by adding Hydrogen to the feed and running it through a catalyst bed.
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Hydrodesulfurisation and ring opening requires mostly proprietary catalyst blends. Historically, straight zeolite in a suitable shape for maximum surface area was used.
With cleaning issues, efficiency requirements, and the desire for extended operation between cleaning, different combinations of noble metals are used. For example, cobalt, molybdenum, vanadium, and nickel.
Cleaning is a process of reducing the spent catalyst with hydrogen, you can also use CO to remove iron and nickel carbonyls. Nitric acid can be used, along with various alkaline leaching. There are advantages and disadvantages to each process.
Engineering work is done constantly to determine the best type of catalyst and cleaning cycle. It's very much a work in process. As the price of crude goes up, there is strong initiative to increase efficiency in this area
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95_GSX previously said:
Also a catalyst is regenerated or replaced, it isn't "blown down".
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Poorly worded on my part. Work is busy lately, I don't have much time to spend on the forum. I was intending to refer to boiler blowdown and cooling tower blowdown
Consumption of rare earth metals can be a major expense for a refinery
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95_GSX previously said:
On another note: The cost to oil companies in upgrades to their process units in order to produce ULSD was very high and required extremely large capital investments. This is part of the reason you see the prices on diesel you do, they have to get that investment back. Thank your local tree hugging hippie and government official for those ULSD requirements.
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What I find interesting is that the hippie tree huggers mandated ULSD in the EU market before the North American market. However, due to different tax structures, diesel fuel is usually cheaper than regular unleaded. That explains why upwards of 45% of the EU passenger car fleet is diesel
Just curious if your facility still has a lot of 5-15 psi pneumatic control, or 4-20 mA analog PID loop control? In the mid 80's I was with Honeywell and we put in quite a few TDC 3000 DCS's, especially overseas.
By the late 1990's a lot of clients were specing Siemens Simatic PCS 7 systems. Digital neworked loop control has many efficiency advantages
Most of my work in the past 6 years has been overseas with new facilities, putting in Foundation FieldBus digital control network, primarily in new facilities. For example, the SECCO facility near Shanghai, was a two year project from greenfield to complete
The SECCO is like a lot of refineries built in the past 5 years. It can go from cold start to inspec in one shift