The reason why the existing aftermarket aux tanks are made from aluminum is that it is by far the lowest cost way to make them, in the low quantities they sell at.
My main incentive for adding one (haven't yet, but promising myself, "soon, soon!"), is for less range anxiety. There are areas with few enough gas stations that it becomes necessary to keep extra track of the status and re-fill early, like when the small tank still has a lot in it, before proceeding, because it will be more than 100 miles to the next town. Those times especially it would be appreciated.
Regarding fill time, it would just be nice to not have to stop and do it so often, even if the larger capacity would make the actual fill time almost as long (only have to get off and stop, half as often).
Norm "performance endurance anxiety" Kerr